Spider-Man - Season 1 - Eps 2: Sub-Zero for Spidey
On a blistering hot afternoon, Peter is walking to the house of a brilliant scientist, Doctor Smartyr, when suddenly he notices that the sidewalk, and most of the neighborhood, is turning to ice. Hearing desperate cries for help from Smartyr's house, Peter changes into Spider-Man and breaks through a laboratory window to find the frightened scientist being menaced by a towering ice creature.
About Spider-Man

Title: Spider-Man
First Air Date: 1967-09-09
Last Air Date: 1970-06-14
Status: Ended
Rating: 7.7/10 (from 193 votes)
Language: EN
Seasons: 3
Total Episodes: 77
Network: ABC Syndication
Genres: Kids, Animation, Action & Adventure
Production Companies: Grantray-Lawrence Animation, Krantz Animation
Synopsis
The bite of a radioactive spider transforms a teen into a superhero.
Cast

Bernard Cowan
Narrator (voice)

Paul Soles
Peter Park / Spider-Man (voice)

Paul Kligman
J. Jonah Jameson (voice)

Peg Dixon
Mary Jane Watson / May Parker / Betty Brant (voice)

Billie Mae Richards
Paperboy (voice) (uncredited)

Corinne Conley

Larry D. Mann

Len Carlson
Green Goblin (voice) (uncredited)