The Man from U.N.C.L.E. - Season 1 - Eps 1: The Vulcan Affair
After a THRUSH attempt to kill Waverly is thwarted, Solo is assigned to prevent the assassination of a visiting African premier (William Marshall) at the hands of Andrew Vulcan (Fritz Weaver), and with the help of a housewife (Patricia Crowley) he learns that the premier himself is allied with THRUSH and plans to kill his two top aides (Ivan Dixon and Rupert Crosse) in a fake accident.
About The Man from U.N.C.L.E.

Title: The Man from U.N.C.L.E.
First Air Date: 1964-09-22
Last Air Date: 1968-01-15
Status: Ended
Rating: 7.2/10 (from 63 votes)
Language: EN
Seasons: 5
Total Episodes: 105
Network: NBC
Genres: Action & Adventure, Comedy, Sci-Fi & Fantasy
Production Companies: MGM Television, Arena Productions
Synopsis
Agents Napoleon Solo and Illya Kuryakin work for a secret intelligence service working under the auspices of the U.N. Their immediate superior is Mr. Waverly. Together they operate out of a secret base beneath the streets of New York City, and accesses through several cover business such as Del Floria's Tailor Shop and the Masque Club. This secret intelligence service is called U.N.C.L.E. United Network Command for Law and Enforcement.
Cast

Robert Vaughn
Napoleon Solo

David McCallum
Illya Kuryakin

Leo G. Carroll
Alexander Waverly