The Man from U.N.C.L.E. - Season 1 - Eps 22: The See-Paris-and-Die Affair
Solo uses the former girlfriend (Kathryn Hays) of 2 brothers, Joseph and Max Van Schreetan (Gerald Mohr, Lloyd Bochner), to thwart their plan to control the diamond market, while at the same time THRUSH agent Corio (Alfred Ryder) tries to steal their cache of gems.
About The Man from U.N.C.L.E.

Title: The Man from U.N.C.L.E.
First Air Date: 1964-09-22
Last Air Date: 1968-01-15
Status: Ended
Rating: 7.2/10 (from 63 votes)
Language: EN
Seasons: 5
Total Episodes: 105
Network: NBC
Genres: Action & Adventure, Comedy, Sci-Fi & Fantasy
Production Companies: MGM Television, Arena Productions
Synopsis
Agents Napoleon Solo and Illya Kuryakin work for a secret intelligence service working under the auspices of the U.N. Their immediate superior is Mr. Waverly. Together they operate out of a secret base beneath the streets of New York City, and accesses through several cover business such as Del Floria's Tailor Shop and the Masque Club. This secret intelligence service is called U.N.C.L.E. United Network Command for Law and Enforcement.
Cast

Robert Vaughn
Napoleon Solo

David McCallum
Illya Kuryakin

Leo G. Carroll
Alexander Waverly