The Man from U.N.C.L.E. - Season 2 - Eps 25: The King of Diamonds Affair
Solo and Illya discover that the world diamond market is being affected by a gang of English criminals headed by Blodgett, who smuggle diamonds inside pudding sold unwittingly by Victoria Poque. They enlist the aid of a master diamond thief, Rafael Delgado. Solo and Victoria end up in Brazil, with Solo tied to the front of a cannon and about to be executed.
About The Man from U.N.C.L.E.

Title: The Man from U.N.C.L.E.
First Air Date: 1964-09-22
Last Air Date: 1968-01-15
Status: Ended
Rating: 7.2/10 (from 63 votes)
Language: EN
Seasons: 5
Total Episodes: 105
Network: NBC
Genres: Action & Adventure, Comedy, Sci-Fi & Fantasy
Production Companies: MGM Television, Arena Productions
Synopsis
Agents Napoleon Solo and Illya Kuryakin work for a secret intelligence service working under the auspices of the U.N. Their immediate superior is Mr. Waverly. Together they operate out of a secret base beneath the streets of New York City, and accesses through several cover business such as Del Floria's Tailor Shop and the Masque Club. This secret intelligence service is called U.N.C.L.E. United Network Command for Law and Enforcement.
Cast

Robert Vaughn
Napoleon Solo

David McCallum
Illya Kuryakin

Leo G. Carroll
Alexander Waverly