Digimon: Digital Monsters - Season 1 - Eps 40: Enter the Dark Masters
As the DigiDestined return to the Digital World, they encounter Chuumon, who tells them that the Dark Masters have taken over the Digital World while they were in Tokyo. The DigiDestined face the Dark Masters, who overpower their Digimon, and Chuumon sacrifices himself to protect Mimi. Pixiemon arrives to save the DigiDestined, sacrificing himself to allow them to escape.
About Digimon: Digital Monsters

Title: Digimon: Digital Monsters
First Air Date: 1999-03-07
Last Air Date: 2001-03-25
Status: Ended
Rating: 8.1/10 (from 845 votes)
Language: JA
Seasons: 2
Total Episodes: 104
Network: Fuji TV
Genres: Animation, Action & Adventure, Sci-Fi & Fantasy, Kids
Production Companies: Toei Animation, Toei Company
Synopsis
While at summer camp, seven kids are transported to a strange digital world. In this new world they make friends with creatures that call themselves Digimon who were born to defend their world from various evil forces.
Cast

Reiko Kiuchi
Daisuke Motomiya (voice)

Megumi Urawa
Iori Hida / Armadimon (voice)

Rio Natsuki
Miyako Inoue (voice)

Hiroaki Hirata
Takeru Takaishi (voice)

Romi Park
Ken Ichijouji / Digimon Kaiser (voice)

Junko Noda
V-mon (voice)

Kae Araki
Hikari Yagami (voice)

Koichi Tochika
Hawkmon (voice)

Miwa Matsumoto
Patamon (voice)

Naozumi Takahashi
Wormmon (voice)