Marvel's Ultimate Spider-Man - Season 3 - Eps 15: S.H.I.E.L.D. Academy
The S.H.I.E.L.D. Academy has been opened up at the Triskelion by Nick Fury as Spider-Man's group gets their education from Mr. Frank and guest instructors like Captain America and Hawkeye. Halfway into their education, Spider-Man and Iron Spider unknowingly reactivate an old World War II villain named Arnim Zola.
About Marvel's Ultimate Spider-Man

Title: Marvel's Ultimate Spider-Man
First Air Date: 2012-04-01
Last Air Date: 2017-01-07
Status: Ended
Rating: 7.677/10 (from 1000 votes)
Language: EN
Seasons: 4
Total Episodes: 103
Network: Disney XD
Genres: Kids, Action & Adventure, Animation, Comedy, Family
Production Companies: Destiny, Marvel Animation
Synopsis
While being trained by S.H.I.E.L.D., Spider-Man battles evil with a new team of teen colleagues.
Cast

Drake Bell
Peter Parker / Spider-Man (voice)

Misty Lee
Aunt May Parker (voice)

J.K. Simmons
J. Jonah Jameson (voice)

Chi McBride
Nick Fury (voice)

Ogie Banks
Luke Cage / Power Man (voice)