Fate/stay night - Season 1 - Eps 23: The Holy Grail
After the incident at the church, Saber and Shirou return home only to find Rin on the floor and badly injured. It turns out that Kirei Kotomine attacked her, while Shirou and Saber were occupied and that's not all because he has also taken Ilya and plans to make her the sacrifice for the Holy Grail. Aided with Rin's final advice, they both head to Ryudouji where Kirei is going to summon the Holy Grail. Saber will battle again with Gilgamesh and Shirou will have to leave her and deal with Kirei, who obviously has some sort of personal vendetta against Shirou.The final fight has just begun.
About Fate/stay night

Title: Fate/stay night
First Air Date: 2006-01-07
Last Air Date: 2006-06-17
Status: Ended
Rating: 7.3/10 (from 209 votes)
Language: JA
Seasons: 2
Total Episodes: 24
Network: Teletama
Genres: Animation, Sci-Fi & Fantasy, Action & Adventure
Production Companies: Studio Deen, Notes
Synopsis
Shirou Emiya lost his parents in a fire when he was young and was later adopted by the sorcerer Kiritsugu Emiya. Shirou is drawn into the Holy Grail War summons a female "Servant" known as Saber to protect him and obtain the Holy Grail.
Cast

Noriaki Sugiyama
Shirou Emiya (voice)

Ayako Kawasumi
Saber (voice)

Kana Ueda
Rin Tohsaka (voice)